I would say that your cell design is important to support the 100 calls. As the base stations will handle 8 simultaneous voice channels. Check that you will have sufficient base stations covering each area for the number of expected simultaneous users in that area.
I did check the IP DECT R4 section in the knowledge base and I did't see any limitation on the IP Line (H.323 Trunk) between the DECT and IP Office.
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